Use explosion-proof electrical/ventilating/lighting/ equipment. Alcohols can be protected as their pivaloyl (Pv) esters by reaction with the anhydride in the presence of MgBr2 - Et3N or Sc(OTf)3 in acetonitrile: J. Org. Precautionary Statements: Consult a doctor. The Propanoic acid,2,2-dimethyl-, 1,1'-anhydride, with the CAS registry number 1538-75-6, is also known as 2,2,2-Trimethylacetic anhydride. According to the concept presented, esters forming an amide (peptide) bond by the mechanism SN#DN or SN#*DN involving fast decay of the tetrahedral intermediate may behave as 'superactive acylating re Bioorg. Prevent further spillage or leakage if it is safe to do so. (M-F, 8AM-5PM EST) TRIMETHYLACETIC ANHYDRIDE MSDS(Chinese) Safety Information. May cause respiratory irritation. . Keep, Remove your current shopping cart and replace with the saved cart? All Rights Reserved. >> : AC162440000; AC162440010; AC162440500; AC162442500 CAS-No 1538-75-6 Synonyms Pivalic anhydride Recommended Use Laboratory chemicals. Trimethylacetic anhydride is used as acylation and esterification reagents. Synonym(s): Pivalic anhydride, 2,2-Dimethylpropionic anhydride. Could peptide synthesis be improved by inventing superactive esters? Chem. (For reference only, please check. : AC162440000; AC162440010; AC162440500; AC162442500 CAS-No 1538-75-6 Synonyms Pivalic anhydride Recommended Use Laboratory chemicals. Lett. Shop Trimethylacetic anhydride, 99%, Thermo Scientific at Fishersci.at. Density 0.918 g/mL at 25 C (lit.) Selling Leads | Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours). endobj ), IATA: UN2920 (For reference only, please check. Size Price ($) Quantity Availability; B22983-14: 25g: 54.92: B22983-22: 100g: 154.35: B22983-36: . email: ecommerce@alfa.com, Specialty/Bulk Sales The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Consult a doctor. 4 0 obj SECTION 1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION. P240 Ground and bond container and receiving equipment. Wash off with soap and plenty of water. Trimethylacetic anhydride. Validity of the model: 1. . Avoid contact with skin and eyes. Emergency CHEMTREC Phone: (800) 424-9300 United States / 001-703-527-3887 International and Maritime . Phone: (803) 278-3504 . SDS Samples of Trimethylacetic anhydride [ CAS# 1538-75-6 ] Product Info: Product Name: Trimethylacetic anhydride. Articles of trimethylacetic formic anhydride are included as well. Remove contact lenses, if present and easy to do. Wear tightly fitting safety goggles with side-shields conforming to EN 166(EU) or NIOSH (US). Rinse with pure water for at least 15 minutes. SAFETY DATA SHEET Creation Date 14-May-2010 Revision Date 24-Dec-2021 Revision Number 5 1. It is also employed in the production of cyano-4, N-tert-butyloxycarbonyl piperidine. Shop Trimethylacetic anhydride, 99%, Thermo Scientific at Fishersci.pt Trimethylacetic anhydride, 99%, Thermo Scientific: Organic oxygen compounds Organic Compounds | Fisher Scientific English Identification Product Name Trimethylacetic anhydride Cat No. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. << P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. It is also used in solid-phase oligonucleotide synthesis and in the kinetic resolution of racemic 2-hydroxy-gamma-butyrolactones with diphenylacetic acid. It does not represent any guarantee of the properties of the product. Ground/bond container and receiving equipment. ), Toxicity to daphnia and other aquatic invertebrates: no data available, Toxicity to microorganisms: no data available, ADR: European Agreement concerning the International Carriage of Dangerous Goods by Road, RID: Regulation concerning the International Carriage of Dangerous Goods by Rail, IMDG: International Maritime Dangerous Goods, IATA: International Air Transportation Association, IPCS - The International Chemical Safety Cards (ICSC), website: http://www.ilo.org/dyn/icsc/showcard.home, HSDB - Hazardous Substances Data Bank, website: https://toxnet.nlm.nih.gov/newtoxnet/hsdb.htm, IARC - International Agency for Research on Cancer, website: http://www.iarc.fr/, eChemPortal - The Global Portal to Information on Chemical Substances by OECD, website: http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en, CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple, ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp, ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: http://www.phmsa.dot.gov/hazmat/library/erg, Germany GESTIS-database on hazard substance, website: http://www.dguv.de/ifa/gestis/gestis-stoffdatenbank/index-2.jsp, ECHA - European Chemicals Agency, website: https://echa.europa.eu/. Keep, Replace your shopping cart with these items? stream Molecular FormulaC10H18O3. Keep cool. P241 Use explosion-proof [electrical/ventilating/lighting/] equipment. "R}~Q:~pgg'"l/O:OV~ @zo7g;)K;=d'}z8}7w7?Iuw?w~ikK^^'d4k;g_u_LOC6($uiz["Dw#u`^D23uOxT~Oi"v?`"DqXmImPiww#({LDo^/w;?EW>;b$l/fmQ-1GG/jls}>"oe6bf.f`:O?e;h@8}u#?LOQ{{{?E_"u_/@o8NKL5A4#AcrwA}tzY- `C&Rl%@Y#;e4 __VF. Classification of the Substance or Mixture: Acute toxicity, Inhalation (Category 2) Skin irritation (Category 1A) Serious eye damage (Category 1) (M-F, 8AM-5PM EST) Causes severe skin burns and eye damage. Collect and arrange disposal. Buying Leads | Use non-sparking tools. Revision Date: July 13, 2015. endobj Gloves must be inspected prior to use. Uses advised against Food, drug, pesticide or biocidal . Size Unit Price Philadelphia, PA Portland, OR Japan* Quantity; 25ML: $52.00. Telephone Support. About Us | /Producer(Sub Systems, Inc.)/CreationDate(D:20211227095835+05'00')/ModDate(D:20211227095835+05'00')/Creator(Sub Systems, Inc.) You can disable the usage of cookies by changing the settings of your browser. Trimethylacetic anhydride Revision Date 14-February-2020 Precautionary Statements Manufacturer Alfa Aesar Thermo Fisher Scientific Chemicals, Inc. 30 Bond Street, Ward Hill, MA 01835-8099 Tel: 800-343-0660 Fax: 800-322-4757 Email: tech@alfa.com www.alfa.com Prevention Keep away from heat, hot surfaces, sparks, open flames and other ignition . Trimethylacetic anhydride, 99%, ACROS Organics 50mL; Glass bottle Chemicals:Organic Compounds:Organic oxygen compounds:Organic oxides Immediately call a POISON CENTER or doctor/physician. Chemsrc provides TRIMETHYLACETIC ANHYDRIDE(CAS#:1538-75-6) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. <> Do not induce vomiting. Trimethylacetic anhydride | 1538-75-6 C10H18O3 structure,synthetic routes, physical and chemical properties, safety information, toxicity, customs data,maps, MSDS, generation methods and uses, and Trimethylacetic anhydride'supstream and downstream products. Handle with gloves. Ensure adequate ventilation. Keep container tightly closed. Discharge into the environment must be avoided. Use personal protective equipment.Wear chemical impermeable gloves. P301+P330+P331 IF SWALLOWED: Rinse mouth. (We`ll never share your email address with a third-party.). No smoking. . Identification Product Name Trimethylacetic anhydride Cat No. Box 219, Batavia, IL 60510 (800) 452-1261 Chemtrec Emergency Phone Number: (800) 424-9342 Product Name Trimethylacetic anhydride Structure CAS 1538-75-6 Synonyms 2,2-Dimethylpropionic anhydride, Pivalic anhydride Category Acylation Reagents Molecular Formula C10H18O3 Molecular Weight 186.25 Physical State Liquid Boiling Point 193 C (lit.) Take off contaminated clothing immediately. Identification Product Name Trimethylacetic anhydride Cat No. MSDS Download MSDS COA Download COA Spec Sheet Trimethylacetic anhydride ( ) Catalog No. Med. : B22983 Synonyms Pivalic anhydride CAS-No . Continue rinsing. Use only non-sparking tools. CAS Registry Number: 1538-75-6: Molecular Formula: C10H18O3: Molecular Weight: 186.25: More information of Trimethylacetic anhydride: Suppliers of Trimethylacetic anhydride : Source: Acetic anhydride SDS Safety Data Sheet for Acetic anhydride 822278 Material Safety Data Sheet or SDS for Acetic anhydride 822278 from Merck for download or viewing in the browser. 1 0 obj Trimethylacetic anhydride Hazmat 99% C of A SDS Catalog Number: 02352 Synonyms: Pivalic anhydride 2,2-Dimethylpropionic acid anhydride Purity Limit: 99% Molecular Formula: C10H18O3 Molecular Weight: 186.25 CAS No: 1538-75-6 MDL No: MFCD00008842 Appearance: Clear colorless liquid Boiling Point: 193C Flash Point: 57C Density: 0.92 Molecular Formula: C10H18O3, MW: 186.25 Specification; Product: CAS Number: 1538-75-6: Molecular Formula: C10 H18 O3: Molecular Weight: 186.248: MDL Number: MFCD00008842: Purity: 97%: Catalogue Number J21937. HAZARD(S) IDENTIFICATION . Rinse mouth with water. Warning! In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant, Catalog Sales & Customer Service /Producer(Sub Systems, Inc.)/CreationDate(D:20211227095835+05'00')/ModDate(D:20211227095835+05'00')/Creator(Sub Systems, Inc.) Wash and dry hands. Use spark-proof tools and explosion-proof equipment. % 18162-48-6 872-50-4 Methylene Chloride naphthalene THF Titanium Dioxide. Wear self-contained breathing apparatus for firefighting if necessary. 2015, 10 (4), 853-856. 43 , 312, (1994). Copyright 2022 Alfa Aesar, Thermo Fisher Scientific. Flammable liquid and vapour. Wear suitable protective clothing. The information in this document is based on the present state of our knowledge and is applicable to the product with regard to appropriate safety precautions. Chemsrc provides TRIMETHYLACETIC ANHYDRIDE(CAS#:1538-75-6) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. email: specialquotes@alfa.com, Technical Service SAFETY DATA SHEET Creation Date 14-May-2010 Revision Date 24-December-2021 Revision Number 5 1. sds@halocarbon.com . SAFETY DATA SHEETS According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition . Trimethylacetic anhydride SAFETY DATA SHEET Page 1 / 9 Creation Date 14-May-2010 Revision Date 02-Feb-2021 Version 2 ALFAAB22983 SECTION 1. Set up emergency exits and the risk-elimination area. Match Criteria: Product Name, Keyword. Do NOT induce vomiting. | Journals | Trimethylacetic anhydride is used as acylation and esterification reagents. Fluid, Electrolyte, and Acid-base Balance, View all products of Market Price & Insight, Trade Alert - Delivering the latest product trends and industry news straight to your inbox. P370+P378 In case of fire: Use to extinguish. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Keep the chemical in suitable and closed containers for disposal. Chat now for more business. Store the container tightly closed in a dry, cool and well-ventilated place. Zhu, J. L.; Liu, Y.; Liu, X. Y.; Liu, H. J.; Chen, Y. Multi stimuli-responsive photoluminescent nanocomposite of silver nanoclusters with hyperbranched polyethylenimine derivatives. This database contains currently more than 8000000 chemicals, 16000 MSDS, 10000 IR spectra and more than 2000 suppliers. Its EINECS number is 216-263-1. Purity : >98% (HPLC) COA Datasheet HNMR HPLC MSDS Handing Instructions Group Booking Get Quotation Bulk Inquiry Add to Cart Biological Information Product Name Trimethylacetic anhydride Note Research use only, not for human use. Asian J. Search. ), ADR/RID: I (For reference only, please check. Avoid dust formation. Flash Point: 57 deg C. Danger! : AC162440000; AC162440010; AC162440500; AC162442500 CAS No 1538-75-6 Synonyms Pivalic anhydride Recommended Use Laboratory chemicals. Store apart from foodstuff containers or incompatible materials. Rinse skin with water/shower. Prevent fire caused by electrostatic discharge steam. P363 Wash contaminated clothing before reuse. : AC162440000; AC162440010; AC162440500; AC162442500 CAS No 1538-75-6 Synonyms Pivalic anhydride Recommended Use Laboratory chemicals. Nitinol Nickel Titanium Shape Memory Alloys, Specpure Inorganic Standards for Water Analysis, Specpure Oil-Based Standards for Wear Metal Analysis, Specpure XRF Standards for Petroleum Products, Cellular Growth & Attachment Factors - BT Products, POCO Electron Beam Crucibles & Hearth Shields (Carbon Graphite), Boron, Phosphorus, Silicon, and Sulfur Compounds, Sugars, Steroids, Amino Acids, and Nucleotides, Precious Metal Compounds - Homogeneous Catalysts. Ambient temperatures. Antibodies & Protein Biology Contact China Manufactory Shaanxi Dideu Medichem Co. Ltd for the product TRIMETHYLACETIC ANHYDRIDE. %PDF-1.4 : 1538-75-6; Synonyms: Pivalic anhydride; 2,2-Dimethylpropionic anhydride; Linear Formula: [(CH3)3CCO]2O; Empirical Formula: C10H18O3; find related products, papers, technical documents, MSDS & more at Sigma-Aldrich. I agree To buy Trimethylacetic anhydride 99.5% purity, please contact sales@tnjchem.com Causes eye and skin burns. Shanghai Jizhi Biochemical Technology Co., Ltd, Faceshields;full-face respirator (US);Gloves;Goggles;multi-purpose combination respirator cartridge (US);type ABEK (EN14387) respirator filter, 2915900090 other saturated acyclic monocarboxylic acids and their anhydrides, halides, peroxides and peroxyacids; their halogenated, sulphonated, nitrated or nitrosated derivatives VAT:17.0% Tax rebate rate:9.0% Supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward) MFN tariff:5.5% General tariff:30.0%, 2,2-dimethylpropanoyl 2,2-dimethylpropanoate, 2,2-Dimethylpropionic anhydride,Pivalic anhydride. (M-F, 8AM-7PM EST) Privacy Policy Our site saves small pieces of text information (cookies) on your device in order to deliver better content and for statistical purposes. Molecular Weight186.2481. Trimethylacetic anhydride, 98% advtechind: trimethylacetic anhydride, 99% 100 G: 25 G: 500 G: alfa-chemistry: Trimethylacetic anhydride, 97% 1g: 5g: 10g: 25g: 100g: 250g: Properties grade purum assay 98.0% (GC) refractive index Please select Language. Pivalic anhydride is included in Organic Reagents category. Do not breathe dust/fume/gas/mist/vapours/spray. Articles of TRIMETHYLACETIC ANHYDRIDE are included as well. X`I%&/m{JJt`$@iG#)*eVe]f@{{;N'?\fdlJ!?~|? Protein Res. Do not discharge to sewer systems. Move the victim into fresh air. 4 0 obj Trimethylacetic anhydride. Catalog Number: CS-T-62444: CAS Number: 1538-75-6: Status: Available for immediate dispatch IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. "R}~Q:~pgg'"l/O:OV~ @zo7g;)K;=d'}z8}7w7?Iuw?w~ikK^^'d4k;g_u_LOC6($uiz["Dw#u`^D23uOxT~Oi"v?`"DqXmImPiww#({LDo^/w;?EW>;b$l/fmQ-1GG/jls}>"oe6bf.f`:O?e;h@8}u#?LOQ{{{?E_"u_/@o8NKL5A4#AcrwA}tzY- `C&Rl%@Y#;e4 __VF. Chemical Properties: clear colourless liquid: Uses: Trimethylacetic anhydride was used: in solid-phase oligonucleotide synthesis; in kinetic resolution of racemic 2-hydroxy--butyrolactones with diphenylacetic acid Shop Trimethylacetic anhydride, 99%, Thermo Scientific at Fishersci.be Trimethylacetic anhydride, 99%, Thermo Scientific: Organic Building Blocks Chemicals | Fisher Scientific English Trimethylacetic anhydride Manufacturer/High quality/Best price/In stock Cas No: 1538-75-6: USD $ 3.0-3.0 / Kilogram: 1 Kilogram: 1-100 Metric Ton/Month: . Observation and elimination of N-acetylation of oligonucleotides prepared using fast-deprotecting phosphoramidites and ultra-mild deprotection. ), IMDG: UN2920 (For reference only, please check. Call a doctor or Poison Control Center immediately. Disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. 400-158-6606. (For reference only, please check. Aldrich-143502; Trimethylacetic anhydride 0.99; CAS No. Tel: 1-888-343-8025 or 1-978-521-6401 IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING :, 99% Product Description: Trimethylacetic anhydride Cat No. Various optically active 2-hydroxy--butyrolactone derivatives are produced via the kinetic resolution of racemic 2-hydroxy--butyrolactones with diphenylacetic acid using pivalic anhydride and (R)-be Int. M12174 CAS No. ACETIC FORMIC ANHYDRIDE [Acetic Acid, Anhydride with Formic Acid] Sodium Formate ID: C1-185; Formylation of Amines; The Dehydration of Alcohols in the Presence Of; United States Patent (19) N; De-Icing Agents for on Station Use Date October 2006 Page 2 of 57; Safety Data Sheets << SynonymsTrimethylacetic anhydride;Pivalic anhydride; 2,2-dimethylpropanoic anhydride. 1538-75-6 SDS. Fax: 1-978-521-6366 Evacuate personnel to safe areas.Keep people away from and upwind of spill/leak. Properties P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. purum, 98.0% (GC) Synonym (s): 2,2-Dimethylpropionic anhydride Linear Formula: [ (CH3)3CCO]2O CAS Number: 1538-75-6 Molecular Weight: 186.25 Beilstein: 386552 EC Number: 216-263-1 MDL number: MFCD00008842 PubChem Substance ID: 24887588 Pricing and availability is not currently available. Inquriy. Moisture Sensitive. ), IMDG: I (For reference only, please check. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Uses advised against Food, drug, pesticide or . Shop Trimethylacetic anhydride, 99%, Thermo Scientific at Fishersci.co.uk Trimethylacetic anhydride, 99%, Thermo Scientific: Organic Building Blocks Chemicals | Fisher Scientific English Take precautionary measures against static discharge. Trimethylacetic Anhydride; Documents: SDS | Specifications | C of A & Other Certificates | Analytical Charts. H226-H314-H335. Email or Live Chat +44 (0) 1928 710 200. P210-P233-P235-P240-P241-P242-P243-P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P370+P378q-P501c, Keep away from heat/sparks/open flames/hot surfaces. RSC Adv. trimethyl-acetic acid Pivalic acid, 99% DSSTox_CID_6432 tert-Butyl carboxylic acid 2,2 dimethylpropanoic acid EC 200-922-5 SCHEMBL3613 DSSTox_RID_78111 2,2,-dimethylpropionic acid 2,2,2-trimethylacetic acid DSSTox_GSID_26432 4-02-00-00908 (Beilstein Handbook Reference) CHEMBL322719 ZINC7993 Dimethylpropionic acid (Related) DTXSID8026432 See also Trimethylacetyl chloride, A15051 . Try our best to find the right business for you. Do not use mouth to mouth resuscitation if the victim ingested or inhaled the chemical. J. Pept. P316 Get emergency medical help immediately. We provide Pivalic anhydride safety data sheet view and download for free at Echemi.com. Clear, Allyl bromide, 99%, stab. P403+P235 Store in a well-ventilated place. ), IATA: I (For reference only, please check. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. Chemsrc provides trimethylacetic formic anhydride(CAS#:10535-67-8) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. Remove all sources of ignition. : 1538-75-6. We offer quality Pharmaceuticals & Chemicals +86 13028999550; info@slpharmachem.com; Espaa; Home; . Safety Data Sheet (SDS) Language. Use dry chemical, carbon dioxide or alcohol-resistant foam. stream Tel: 1-800-343-7276 or 1-978-521-6405 >> The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. email: tech@alfa.com. Our team of scientists has experience in all . Do not let the chemical enter drains. Wear fire/flame resistant and impervious clothing. Availability: Please inquire. Acetic Anhydride Flinn Scientific, Inc. P.O. Wash contaminated clothing before reuse. Lett., 1143 (1998). SAFETY DATA SHEET Creation Date 14-May-2010 Revision Date 24-Dec-2021 Revision Number 5 1. Specifications . : 1538-75-6 Formula: C10h18o3 EINECS: 216-263-1 Type: Pharmaceutical Intermediates Appearance: Liquid Colour: Colorless Never give anything by mouth to an unconscious person. ), IMDG: CORROSIVE LIQUID, FLAMMABLE, N.O.S. X`I%&/m{JJt`$@iG#)*eVe]f@{{;N'?\fdlJ!?~|? TMA can derivatize unmodified amine groups of lysine residues and amine groups generated at peptide N-termini by trypsin digestion. Symbol: GHS02, GHS05: Signal Word: Danger Hazard Statements: H226-H314 . Trimethylacetic anhydride 99% Synonym (s): Pivalic anhydride, 2,2-Dimethylpropionic anhydride Linear Formula: [ (CH3)3CCO]2O CAS Number: 1538-75-6 Molecular Weight: 186.25 Beilstein: 386552 EC Number: 216-263-1 MDL number: MFCD00008842 PubChem Substance ID: 24848589 NACRES: NA.22 Pricing and availability is not currently available. << Structured search. Catalog Number 822278 Product Name Acetic anhydride Select Language If you are not able to see the SDS please use this link to download it: Download SDS View catalogue prices, chemical data, technical specifications and SDS documents. Fax: 1-800-322-4757 SDS Pricing; 901602: 1 M in dichloromethane: Expand. SAFETY DATA SHEET Creation Date 14-May-2010 Revision Date 24-December-2021 Revision Number 5 1. ChemicalBook ProvideIsobutyric anhydride(97-72-3) Raman,IR2,MS,IR3,IR,1H NMR,Raman,ESR,13C NMR,Spectrum. P321 Specific treatment (see on this label). Identification Product Name Trimethylacetic anhydride Cat No. TRIMETHYLACETIC ANHYDRIDE Synonyms:Pivalic anhydride;MFCD00008842;2,2-dimethylpropanoyl 2,2 . Chem. Keep cool. Chem., 61, 5702 (1996). 1. CAS No. Applicability domain: Because an experimental boiling point is available the applicablity domain is just described by the molecular weight range. Buy Trimethylacetic Anhydride (CAS 1538-75-6), a specialty product for proteomics research, from Santa Cruz. We as supplier shall not be held liable for any damage resulting from handling or from contact with the above product. Uses advised against Food, drug, pesticide or . H314 Causes severe skin burns and eye damage. Defined Endpoint: Vapour pressure 2. Technical Service. Avoid breathing mist, gas or vapours.Avoid contacting with skin and eye. Hazard Statements: 2. P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. or 1-978-521-6350 The requested SDS is not available. The concept of superactive esters. Avoid formation of dust and aerosols. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/ P260 Do not breathe dust/fume/gas/mist/vapours/spray. ), IATA: 8 (For reference only, please check. Please Contact Us for more information. Do NOT induce vomiting. Disclaimer, Copyright 2022 ChemSrc All Rights Reserved. Buy Trimethylacetic Anhydride1538-75-6 at CymitQuimica from 80.0 Product Classification | Corrosive. Adhered or collected material should be promptly disposed of, in accordance with appropriate laws and regulations. If breathing is difficult, give oxygen. By browsing our website without changing the browser settings you grant us permission to store that information on your device. . 17 These adducts were then reacted with 4 and stirred for 12-15 h. This process yielded the targeted allylic sulfones 11a-e in fair to good yield (59-98%). 1538-75-6 Used as pharmaceutical intermediates. Request MSDS. Trimethylacetic anhydride CAS 1538-75-6. 11(9) , 1105-1107, (2001). Hide. Handle in accordance with good industrial hygiene and safety practice. Tel: 1-800-343-0660 or 1-978-521-6300 2015, 5 (11), 8146-8151. Trimethylacetic anhydride | C10H18O3 | CID 15234 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological . - No smoking. CAS No. Handling in a well ventilated place. Remove contact lenses, if present and easy to do. 3. Linear Formula: [(CH 3) 3 CCO] 2 O. Terms of Use, Keep your current shopping and add the saved Cart? Here, we introduce use of trimethylacetic anhydride (TMA) as a new reagent for efficient histone derivatization, which is a requirement for bottom-up proteomic hPTM analysis. If the exposure limits are exceeded, irritation or other symptoms are experienced, use a full-face respirator. It is involved in acylation and esterification reactions with anilines and phenols. Articles of TRIMETHYLACETIC ANHYDRIDE are included as well. Look through Pivalic anhydride MSDS details show. with 300-1000ppm Propylene oxide, 1,2,4-Benzenetricarboxylic anhydride, 97%. The direct hydrogenation of carboxylic acids to aldehydes has been achieved in the presence of pivalic anhydride and Tetrakis(triphenylphosphine)palladium(0), 10548 : Chem. Wu, J.; Leng, W. L.; Liao, H.; Hoang, K. L. M.; Le, K.; Liu, X. W. Intramolecular C-N Bond Formation under Metal-free Conditions: Synthesis of Indolizines. %PDF-1.4 Clear, Add the items to your existing shopping cart? Ensure adequate ventilation.Remove all sources of ignition. Buy GK7182 - Trimethylacetic anhydride (1538-75-6) online from Glentham Life Sciences, a manufacturer and supplier of fine chemicals. ), IMDG: 8 (For reference only, please check. SDS Certificate of Analysis Product Specification Technical Inquiry Stock No. Kinetic resolution of racemic 2-hydroxy--butyrolactones by asymmetric esterification using diphenylacetic acid with pivalic anhydride and a chiral acyl-transfer catalyst. ), IATA: CORROSIVE LIQUID, FLAMMABLE, N.O.S. Trimethylacetic Anhydride;2,2-Dimethylpropionic Anhydride;Pivalic Anhydride. % Products: Trimethylacetic anhydride. ICP16009155-1 | Copyright@Qingdao ECHEMI Digital Technology Co., Ltd. Bis-(3-nitrophenyl)-methylphosphine oxide, Arginyl-arginyl-prolyl-tyrosyl-isoleucyl-leucine, 5-Hydroxy-2-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzonitrile, (1R,2S)-2-(3,4-difluorophenyl)cyclopropanamine hydrochloride, N-(2-Methyl-5-nitrophenyl)-4-(3-pyridinyl)-2-pyrimidinamine, 1,1-[(4R)-[4,4-Bi-1,3-benzodioxole]-5,5-diyl]bis[1,1-diphenylphosphine], TRIMETHYLACETIC ANHYDRIDE 99% high purity certified Professional producer Greenbo, Factory Supply High Purity Acetyl chloride 99% CAS 75-36-5, N-BOC-aniline,3422-01-3 99% white white powder, ECHEMI - ECHEMI platform complaint penalty rules, Market Analysis - Monthly Report - July 2022- Hot Products, Price trends in the China's chemical market in the first half of 2022, Soybean Oil and Palm Oil Prices Bottom Out, The country's first "hydrolyzed zinc hyaluronate" was successfully filed, View all products of Market Price & Insight, ADR/RID: UN2920 (For reference only, please check. Commercially available 'fast-deprotecting' phosphoramidites are useful for synthesizing oligonucleotides containing alkali-sensitive nucleotides. P243 Take action to prevent static discharges. 1 0 obj Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Continue rinsing. It is involved in acylation and esterification reactions with anilines and phenols. With a molecular weight of 186.25 g/mole the substance is within the applicable range of 16 - 943 g/mole. However, N-acetylated oligonucleotides were observed d Get all suppliers and price by the below link: Home | MSDS/SDS Database Search | It belongs to the product categories of Aliphatics; Intermediates & Fine Chemicals; Metabolites & Impurities; Pharmaceuticals. You may also SUBMIT your own data! . Find trimethylacetic acid and related products for scientific research at MilliporeSigma. Rinse affected areas with water [or shower]. To pursue the alternate methodology of the trimethylacetic p-toluenesulfinic anhydride, Baylis-Hillman adducts 10a-e were prepared using the method of Aggarwal and coworkers . Trimethylacetic anhydride: : 1,3,5-,2--4-(1-)-6- - 2,2-- , >=98.0% (GC) 100G ( ,99%: : Trimethylacetic anhydride Pivalic anhydride 2,2-dimethylpropanoic anhydride Controlled incineration with flue gas scrubbing is possible for combustible packaging materials. Discounts available on volumes >5x largest . Unambigous algorithm: Themodified Grain methodequation was used for calculation. <> Incompatible with strong oxidizing agents, strong acids, strong bases and strong reducing agents. If not breathing, give artificial respiration and consult a doctor immediately. SDS. ), ADR/RID: CORROSIVE LIQUID, FLAMMABLE, N.O.S. Wear protective gloves/protective clothing/eye protection/face protection. (For reference only, please check. Moisture sensitive. Welcome to chemicalbook! Uses advised against Food, drug, pesticide or biocidal . Acetic Anhydride Safety Data Sheet (SDS) SDS #: 6. Biologically Active Compounds | . P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Fax: 1-978-521-6350 IF SWALLOWED: Rinse mouth. For information in North America, call: 800-ACROS-01 For emergencies in the US, call CHEMTREC: 800-424-9300 Section 2 - Composition, Information on Ingredients Section 3 - Hazards Identification EMERGENCY OVERVIEW Appearance: clear, colorless liquid. Can derivatize unmodified amine groups of lysine residues and amine groups of lysine residues amine... On skin ( or equivalent ) and offered for recycling or reconditioning 0.918 g/mL at 25 C lit. Sds | Specifications | C of a & amp ; Protein Biology contact China Manufactory Dideu! 99.5 % purity, please check please contact sales @ tnjchem.com Causes and! Applicablity domain is just described by the molecular weight of 186.25 g/mole the substance within... Breathing mist, gas or vapours.Avoid contacting with skin and eye p304+p340 if inhaled: Remove to! Skin and eye GHS ) - Sixth revised edition Product Trimethylacetic anhydride ( 97-72-3 Raman..., is also employed in the kinetic resolution of racemic 2-hydroxy -- butyrolactones by asymmetric esterification using acid...: B22983-22: 100g: 154.35: B22983-36: CAS registry Number 1538-75-6, also. Or collected material should be promptly disposed of in a well-ventilated area in acylation and esterification reagents person. ( Chinese ) safety Information, MS, IR3, IR,1H NMR, Spectrum, 99 % Product:! Take off immediately all contaminated clothing Product Name: Trimethylacetic anhydride ( 97-72-3 ),... < > Incompatible with strong oxidizing agents, strong bases and strong reducing.. 1 / 9 Creation Date 14-May-2010 Revision Date 24-December-2021 Revision Number 5 1 with... 2-Hydroxy -- butyrolactones by asymmetric esterification using diphenylacetic acid add the items to your existing cart! 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Ignition sources Information on your device United States / 001-703-527-3887 International and Maritime NIOSH ( ).: 154.35: B22983-36: to do ) - Sixth revised edition we as supplier shall not held. Label ) trypsin digestion chemicalbook ProvideIsobutyric anhydride ( ) Catalog No at Echemi.com damage resulting from handling or contact! To find the right business for you alcohol-resistant foam breathing, give respiration... Anhydride Recommended Use Laboratory chemicals and upwind of spill/leak, hands and any exposed skin thoroughly after handling Use outdoors! Emergency CHEMTREC Phone: ( 800 ) 424-9300 United States / 001-703-527-3887 International and.... With diphenylacetic acid ; AC162440500 ; AC162442500 CAS No 1538-75-6 Synonyms Pivalic anhydride Recommended Use Laboratory chemicals consult a immediately. ( we ` ll never share your email address with a third-party. ) address with a third-party )... P-Toluenesulfinic anhydride, 97 % replace with the above Product 2-hydroxy -- butyrolactones by asymmetric esterification diphenylacetic! Groups of lysine residues and amine groups of lysine residues and amine groups generated at peptide N-termini by trypsin.... Page 1 / 9 Creation Date 14-May-2010 Revision Date 24-Dec-2021 Revision Number 5 1 for! Not be held liable for any damage resulting from handling or from contact with the above.!
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trimethylacetic anhydride sds